TOSCO NORTHWEST COMPANY -- GASOLINE,BP REGULAR UNLEADED OR GASOLINE,REGULAR UNLEADED 87 -- 9150-00-148-7103
===================== Product Identification ===================== Product ID:GASOLINE,BP REGULAR UNLEADED OR GASOLINE,REGULAR UNLEADED 87 MSDS Date:07/22/1994 FSC:9150 NIIN:00-148-7103 === Responsible Party === Company Name:TOSCO NORTHWEST COMPANY Box:8 City:FEMDALE State:WA ZIP:98248-0008 Country:US Info Phone Num:206-348-1011/206-384-8400 Emergency Phone Num:800-424-9300(CHEMTREC)/206-348-1011 CAGE:KO291 === Contractor Identification === Company Name:TOSCO NORTHWEST COMPANY Box:8 City:FEMDALE State:WA ZIP:98248-0008 Country:US Phone:206-348-1011/206-384-8400 CAGE:KO291 ============= Composition/Information on Ingredients ============= Ingred Name:GASOLINE CAS:8006-61-9 RTECS #:LX3300000 Fraction by Wt: 89-100% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM/500STEL;9394 Ingred Name:GASOLINE MAY CONTAIN 1 OR MORE OF THE FOLLOWING INGREDIENTS (#3-8) RTECS #:9999999ZZ Other REC Limits:NONE RECOMMENDED Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 5-7% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: 0-2% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2; 9394 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 0-3% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9394 Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 0-2% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/125STEL;9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CYCLOHEXANE (SARA III) CAS:110-82-7 RTECS #:GU6300000 Fraction by Wt: 0-1% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM, 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 0-11% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9394 Ingred Name:PER MSDS:REMAINING COMPONENTS NOT DETERMINED HAZ &/OR HAZ COMPONENETS PRESENT @LESS THAN 1.0% (0.1% FOR CARCINOGENS). RTECS #:9999999ZZ Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:INGEST:MODERATELY TOXIC.ASPIRATION INTO LUNGS MAY CAUSE PNEUMONITIS.GI DISTURBANCES.HARMFUL CNS EFFECTS.SKIN:PROACTICALLY NONTOXIC.SLIGHTLY IRRIT.REP/PROL CONTACT MAY RESULT IN DERM,POSSIBLE 2ND INFEC TION.HIGH PRESSURE SKIN INJECTIONS ARE SERIOUS MED EMERGENCIES-POSSIBLE SERIOUS DELAYED TISSUE DAMAGE.EYE:SLIGHT-(SUPPL) Explanation of Carcinogenicity:PER MSDS:IARC HAS DETERMINED THAT GASOLINE ENGINE EXHAU POSSIBLY CARCI TO HUMANS(CLASS 2B) & CONTAIN BENZENE (CLASS 1). Effects of Overexposure:INGEST:TOXIC,ASPIRATION INTO LUNGS-PNEUMONITIS,IRRIT,NAU,VOMIT,DIARR,EXCITATION,EUPHORIA,HEADACH E,DIZZ,DROWSINESS,BLURRED VIIONS,FTG,TRMEORS,CONVULSIONS,UNCONSC,COMA,RESP ARREST,DEATH.SKIN:DERM.EYE:TR NASIENT IRRIT.INHAL:ANEMIA,IRREG HEART RHYTHM,BEHAVIORAL CHANGES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:DO NOT INDUCE VOMIT BECAUSE OF DANGER OF ASPIRATING LIQ INTO LUNGS.GET IMMED MED ATTN.IS SPONT VOMIT MONITOR BREATH FOR DIFFICULTY.SKIN:REMOVE CONTAMIN CLOTH IMMED.WASH WELL W/SOAP/WATER.IRRIT PERSIST GET MED ATTN IMMED.HIGH PRESSUREINJECTION ARE SERIOUS MED EMERGENCIES REQUIRING IMMED MED ATTN.EYE:FLUSH IMMED W/LG AMTS OF WATER FOR @LEAST 15MINS OPENING EYELIDS.IRRIT RESULTS GET MED (SUP) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=-37.2C, -35.F Lower Limits:1.4 Upper Limits:7.6 Extinguishing Media:USE DRY CHMEICL, ALL PURPOSE AFFF, ALCOHOL FOAM OR CARBON DIOXIDE TO EXTINGUISH FIRE.WATER MAY BE INEFFECTIVE. Fire Fighting Procedures:COOL FIRE-EXPO CNTBNRS/STRUCTURES/PROT PEOPLE/KEE MATL AWAY FRM IGN SOURCES WHEN SPILL W/WATER.FOAM BLANKETS TO REDUCE VAP/PROT WORKERS.WEAR +PRESS SCBA/ (SUPP) Unusual Fire/Explosion Hazard:DANGEROUS WHEN EXPOSED TO HEAT/FLAMES.RUNOFF TO SEWER MAY CUASE FIRE OR EXPLOSION HAZARD.CONTAINERS MAY EXPLODE IF HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:ACTIVATE EMERG SPILL PLAN/NOTIFY OIL SPILL INTO WATERS TO NAT RESP CNTR.STOP SPILL W/O RISK.STAY UPWIND/OUT OF LOW AREAS.USE PPE.ISOLATE/DENY ENTRY.REMOVE IGN SOURCES.SUPPRESS VAP W/FIRE FOAM BLANKET. CONTAIN/DIKE.USE SAND/OTHER ABSORB FOR SM SPILL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN NFPA APPROVED CLEARLY LABELED CNTNR TIGHTLY CLSD NEVER IN GLASS/UNAPPROVED PLASTIC CNTNR.STORE IN COOL DRY ISOLATED WELL VENTI AREA. Other Precautions:EMPTY CNTNR CAN BE HAZ.USE ONLY AS MOTOR FUEL.STORE AWAY FRM IGN SOURCES.GROUND WHEN TRANSF.MATL CONTAINS:SARA TITLE III CHEM,INGRED KNOWN TO STATE OF CA TO CAUSE CANCER,BIRTH DEFECTS,OTHER REPROD HAR M,SUBSTANCE LISTED AS HAZ AIR POLLUTANT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ADEQUATE VENTILATION WHERE POSSIBLE. IF VENTILATION IS NOT ADEQUATE TO REDUCE EXPO BELOW PERMISSIBLE LIMITS OR IF IRRITATION IS EXPERIENCED NIOSH APPROVED RESP PROTECTIN SHOULD BE WORN. Ventilation:USE ADEQUATE VENTILATION. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:SAF GLASSES, CHEM GOGG. Other Protective Equipment:EYEWASH STATION.PROT CLOTH(COVERALL,LAB APRONS)AS NEEDED.SOLVT BARRIER CREMES MAY BE USED TO SUPLEMENT IMPERV GLOVES. Work Hygienic Practices:WASH CONTAMIN CLOTH BEF REUSE.WASH WORK CLOTH REG.USE GOOD PERSONAL HYGIENE PRACTICES.WASH HANDS BEF EAT/DRINK/SMOKE/TOI Supplemental Safety and Health FSC IS WRONG. SEE RECORD WITH FSC 9130. FIREFIGHTING:FULLFACEMASK/FLAME PROT CLOTH. HEALTH HAZ:MODERATE TRANSIENT IRRIT.INHAL:RESP TRACT IRRIT.ANEMIA,IRREG HEART RHYTHM.REP/PROL EXPO MAY CAUSE BEHAVIO RAL CHANGES. 1STAID:ATTN.INHAL:REMOVE FROM EXPO SOURCE.NOT BREATH GIVE ART RESP/CPR.ADMIN OXY.GET IMMED MED ATTN. ================== Physical/Chemical Properties ================== HCC:F1 Boiling Pt:=-2.9C, 26.7F Vapor Pres:760 @100F Vapor Density:1.2 Spec Gravity:0.72-0.74 @60F Evaporation Rate & Reference:>1, WATER=1 Appearance and Odor:CLEAR TO AMBER LIQUID WITH A STRONG HYDROCARBON ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZERS. Stability Condition to Avoid:IGNITION SOURCES. Hazardous Decomposition Products:BURNING MATL WILL EMIT IRRIT & TOXIC SUBSTANCES. COMBUSTION MAY PRODUCE C0,C02 & REACTIVE HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATL RQ:333LBS.DISCARD/DISPOSED MATL SPECIFICALLY NOT HAZ WASTE HOWEVER CHARACTERISTICALLY HAZ WASTE PER IGN/TOXIC DEFINITION & STATE/LOC REGS.EPA HAZ WASTE NO:D001.CHEM ADDN/PROCESSING/ALTERING MATL MAY MAKE WASTE MGT INFO IN MSDS INCOMPLETE. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.