PHILLIPS 66 CO -- PROPANE HD-5 GRADE, 26164  -- 9150-00N046320
<pre>=====================  Product Identification  =====================

Product ID:PROPANE HD-5 GRADE, 26164
MSDS Date:12/31/1991
FSC:9150
NIIN:00N046320
=== Responsible Party ===
Company Name:PHILLIPS 66 CO
Address:PHILLIPS PETROLEUM CO
City:BARTLESVILLE
State:OK
ZIP:74004
Country:US
Info Phone Num:918-661-8327;918-661-5952
Emergency Phone Num:918-661-3865;918-661-8118
CAGE:GO225
=== Contractor Identification ===
Company Name:PHILLIPS 66 CO
Address:699 ADAMS BLDG
City:BARTLESVILLE
State:OK
ZIP:74004
Country:US
Phone:918-661-8327
CAGE:GO225
Company Name:PHILLIPS 66 COMPANY(DIVISION OF PHILLIPS PETROLEUM CO)
Address:699 ADAMS BLDG 411 KEELER ST
Box:City:BARTLESVILLE
State:OK
ZIP:74004
Country:US
Phone:918-661-8327
CAGE:6Y142

=============  Composition/Information on Ingredients  =============

Ingred Name:ING 17:OTHER FACTS ASSOC W/THE SO-CALLED "ODOR-FADE
    PHENOMENON." IF YOU DO NOT ALREADY KNOW ALL THE FACTS, (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18:WRITE PHILLIPS 66 CO & ASK FOR MORE INFO ABOUT ODOR
    & THE OTHER SAFETY CONSIDERATION ASSOC W/THE HNDLG,  (20)
RTECS #:9999999ZZ

Ingred Name:ING 19:STORAGE AND USE OF PROPANE.
RTECS #:9999999ZZ

Ingred Name:ETHANETHIOL; (ETHYL MERCAPTAN).
CAS:75-08-1
RTECS #:KI9625000
Fraction by Wt: 0-50%PPM
OSHA PEL:0.5 PPM
ACGIH TLV:0.5 PPM

Ingred Name:SUPDAT:EXPLO HAZ:OVER-PRESS (BLEVE). FRAGMENTATION OF THE
    CNTNR SHOULD BE ANTICIPATED. IF FLAME IS AGAINST THE  (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5:CNTNR, WITHDRAW IMMED ON HEARING A RISING SOUND, IF
    VENT INCREASES IN VOL/INTENSITY,/IF THERE IS (ING 7)
RTECS #:9999999ZZ
Other REC Limits:NONE RECOMMENDED

Ingred Name:ING 6:DISCOLORATION OF THE TANK DUE TO FIRE.
RTECS #:9999999ZZ

Ingred Name:ING 7:EFFTS OF OVEREXP:LAB ANIMALS HAVE EXHIBITED HIGHER
    DEGREE OF NARCOS WHEN EXPOS TO BOTH BUTANE & BUTYLENE (ING 9).
RTECS #:9999999ZZ

Ingred Name:ING 8:(ADDITIVE EFFTS), THAN THE DEGREE OF NARCOS EXHIBITED
    FOLLWOING EXPOS TO BUTANE/BUTYLENE ALONE.
RTECS #:9999999ZZ

Ingred Name:OTHER PREC:KEEP CNTNRS CLOSED. CONTACT IMMED SUPERVISOR FOR
    SPECIFIC INSTRUCTIONS BEFORE WORK IS INITIATED ON (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10:CONTAMINATED EQUIP. NOTE:STORE IN CNTNRS THAT HAVE
    BEEN PROPERLY PURGED & PASSIFIED. (OXIDATION OF ETHYL (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:MERCEPTAN MAY OCCUR IN THE PRESENCE OF RUST, AIR, OR
    WATER.) WARNING:BE AWARE THAT WITH ODORIZED PROD (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12:THE INTENSITY OF ETHYL MERCAPTAN STENCH (ITS ODOR)
    MAY FADE DUE TO CHEM OXIDATION (IN THE PRESENCE OF (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13:RUST, AIR OR MOISTURE), ADSORPTION/ABSORPTION SOME
    PEOPLE HAVE NASAL PERCEPTION PROBLEMS & MAY NOT BE (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:ABLE TO SMELL THE ETHYL MERCAPTAN STENCH. OTHER
    ODORS MAY MASK/HIDE THE ETHYL MERCAPTAN STENCH. WHILE (16)
RTECS #:9999999ZZ

Ingred Name:ING 15:ETHYL MERCAPTAN MAY NOT IMPART THE WARNING OF THE
    PRESENCE OF PROPANE IN EVERY INSTANCE, IT IS GENERALLY (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16:EFTIVE IN A MAJORITY OF SITUATIONS. FAMILIARIZE
    YOURSELF, & YOUR CUSTOMERS, WITH THIS WARNING, AND (ING 18)
RTECS #:9999999ZZ

Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: >90%
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE  ASPHYXIANT

Ingred Name:PROPENE; (PROPYLENE) (SARA III).
CAS:115-07-1
RTECS #:UC6740000
Fraction by Wt: <5%
OSHA PEL:N/K 
ACGIH TLV:SIMPLE ASPHIXIANT

Ingred Name:BUTANE; (BUTANES).
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: <2.5%
OSHA PEL:800 PPM
ACGIH TLV:800 PPM

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:SIMPLE ASPHYXIANT. EXTREME
    OVER EXPOS MAY PRDCE DIZZ, HDCH, DISORIENTATION, EXCITATION, FATG,
    INABILITY TO CONC, VOMIT, COUGHING, ANESTH, UNCON & DEATH.
    INGEST:NOT LIKELY EXPO RTE. LIQUEFI ED GAS MAY CAUSE FREEZE BURNS
    TO MUC MEMB & POSS CNS DEPRESS. (EFTS OF OVERPOS)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:EYE VERY HIGH GAS CONCS MAY CAUSE MILD
    IRRIT EFTS. LIQ GAS MAY CAUSE FREEZE BURNS UPON DIRECT CONT.
    SKIN:VERY HIGH GAS CONCS MAY CAUSE MILD IRRIT TO MUC MEMB.
    LIQUEFIED GAS MAY CAUSE FREEZE B URNS UPON DIRECT CONT. (ING 8)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INHAL:IMMED REMOVE FROM EXPO. IF BRTHG IS DFCLT, GIVE OXYG.
    IF BRTHG CEASES, ADMIN ARTF RESP FOLLOWD BY OXYG. SEEK IMMED MED
    ATTN. INGEST:SEEK IMMED MED ATTN. EYE:IMMED FLUSH WITH TAP WATER
    FOR AT LEA ST 15 MINUTES. IF IRRIT DEVEL, SEEK MEDATTN. SKIN:IMMED
    FLUSH WITH TAP WATER FOR FIFTEEN MINUTES. IF IRRIT DEVEL, SEEK MED
    ATTN.

=====================  Fire Fighting Measures  =====================

Flash Point:-156F,-104C
Lower Limits:2.1
Upper Limits:9.5
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE (CO2).
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
    EQUIPMENT . EVACUATE AREA OF ALL UNNEC PERSONNEL. SHUT OFF SOURCE,
    IF POSS. H20 FOG/SPRAY MAY BE (SUPDAT)
Unusual Fire/Explosion Hazard:CARBON & SULFUR OXIDES FORMED WHEN
    BURNED. HIGHLY FLAM VAPS WHICH ARE HVR/AIR MAY ACCUM IN LOW AREAS
    AND/OR SPREAD ALONG GROUND AWAY FROM HNDLG SITE. (SUPDAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:EVACUATE AREA OF ALL UNNECESSARY PERSONNEL.
    WEAR PROT EQUIP AND/OR GARMENTS DESCRIBED IN SEC 8 IF EXPOS COND
    WARRANT. SHUT OFF SOURCE, IF POSS. PROTECT FROM IGNITION. VENT AREA
    THORO.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN/CLTHG. DO
    NOT BRTH VAPS, MISTS, FUMES/DUST. WEAR PROT EQUIP AND/OR GARMENTS
    DESCRIBED IN SECTION 8 IF EXPOS CONDS WARRANT.
Other Precautions:MAY CAUSE FREEZE BURNS UPON DIRECT CONTACT. STORE IN
    A COOL, WELL VENTD AREA AWAY FROM IGNIT SOURCES. PROVIDE MEANS FOR
    CONTROLLING LEAKS. BOND & GROUND DURING TRANSFER. (ING 10)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NOT GENERALLY REQ. WHEN ENTRY INTO/EXIT FROM
    CONC OF UNKNOWN EXPOS, USE NIOSH/MSHA APPROVED SELF-CONTAINED
    BREATHING APPARATUS (SCBA).
Ventilation:USE ADEQUATE VENT TO CONTROL EXPOSURE BELOW RECOMMENDED
    LEVELS.
Protective Gloves:IMPERVIOUS .
Eye Protection:SAFETY GLASSES W/SIDE SHIELDS.
Other Protective Equipment:AVOID UNNEC SKIN CONTAM WITH MATL. WHERE
    SPEC CNDTNS EXIST, SEEK ASSIST OF INDUS HYGIENIST/QUALIFIED
    PROFESSIONAL.
Work Hygienic Practices:WASH THORO AFTER HNDLG. LAUNDER CONTAM CLTHG
    BEFORE REUSE.
Supplemental Safety and Health
SPEC GRAV:0.508-0.510 @ 60/60F(15.6/15.6C). VP:108-124 PSIA @ 70F(21C).
    FIRE FIGHT PROC:USED TO COOL EXPOSED CNTNRS & EQUIP. ALLOW FIRE TO
    BURN UNTIL GAS FLOW IS SHUT OFF, IF POSS. EXPLO HAZ:FLASH BAC K
    ALONG THE VAP TRAIL IS POSS. HEATED CNTNRS MAY RUPTURE VIOLENTLY &
    SUDDENLY W/OUT WARNING DUE TO VESSEL (ING 5)

==================  Physical/Chemical Properties  ==================

HCC:G2
Boiling Pt:B.P. Text:-44F,-42C
Vapor Pres:SUPP DATA
Vapor Density:1.5
Spec Gravity:SUPP DATA
Evaporation Rate &amp; Reference:>1 (ETHYL ETHER =1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUIFIED PETROLEUM GAS.
    ODORLESS(REPULSIVE IF ODORANT HAS BEEN ADDED
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
OXYGEN AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NOT ESTABLISHED.
Hazardous Decomposition Products:CARBON AND SULFUR OXIDES FORMED WHEN
    BURNED.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
    REGULATIONS . INCIN/OTHERWISE MANAGE IN A RCRA PERMITTED WASTE
    MANAGEMENT FACILITY. IGNITABLE (D001).

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
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