| Common Name: | VALVOLINE SAE 30 NON-DETERGENT MOTOR OIL |
| Manufacturer: | ASHLAND CHEMICAL |
| MSDS Revision Date: | 1/24/2008 |
| Grainger Item Number(s): | 1UBY5 |
| Manufacturer Model Number(s): |
MSDS Table of Contents
Click the desired link below to jump directly to that section in the MSDS.
ASHLAND(R*)
SAFETY DATA SHEET
VALVOLINE(R*) SAE 30 NON-DETERGENT MOTOR OIL VV265
REVISION DATE: 01/24/2008
PRINT DATE: 3/6/2008
MSDS NUMBER: R0169702
VERSION: 1.4
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
ASHLAND
P.O. BOX 2219
COLUMBUS, OH 43216
REGULATORY INFORMATION NUMBER: 1-800-325-3751
TELEPHONE: 614-790-3333
EMERGENCY TELEPHONE: 1-800-ASHLAND (1-800-274-5263)
PRODUCT NAME: VALVOLINE(R*) SAE 30 NON-DETERGENT MOTOR OIL
PRODUCT CODE: VV265
PRODUCT USE DESCRIPTION: NO DATA
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
APPEARANCE: LIQUID, AMBER
CAUTION!
PROLONGED OR REPEATED CONTACT MAY DRY THE SKIN AND CAUSE IRRITATION AND
BURNS.
POTENTIAL HEALTH EFFECTS:
ROUTES OF EXPOSURE: NO DATA
EYE CONTACT: UNLIKELY TO CAUSE EYE IRRITATION OR INJURY.
SKIN CONTACT:
MAY CAUSE MILD SKIN IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY THE
SKIN. SYMPTOMS MAY INCLUDE REDNESS, BURNING, DRYING AND CRACKING OF SKIN,
AND SKIN BURNS.
INGESTION:
SWALLOWING SMALL AMOUNTS OF THIS MATERIAL DURING NORMAL HANDLING IS NOT
LIKELY TO CAUSE HARMFUL EFFECTS. SWALLOWING LARGE AMOUNTS MAY BE HARMFUL.
THIS MATERIAL CAN GET INTO THE LUNGS DURING SWALLOWING OR VOMITING. THIS
RESULTS IN LUNG INFLAMMATION AND OTHER LUNG INJURY.
INHALATION:
IT IS POSSIBLE TO BREATHE THIS MATERIAL UNDER CERTAIN CONDITIONS OF
HANDLING AND USE (FOR EXAMPLE, DURING HEATING, SPRAYING, OR STIRRING).
BREATHING SMALL AMOUNTS OF THIS MATERIAL DURING NORMAL HANDLING IS NOT
LIKELY TO CAUSE HARMFUL EFFECTS. BREATHING LARGE AMOUNTS MAY BE HARMFUL.
SYMPTOMS ARE NOT EXPECTED AT AIR CONCENTRATIONS BELOW THE RECOMMENDED
EXPOSURE LIMITS, IF APPLICABLE (SEE SECTION 8.).
AGGRAVATED MEDICAL CONDITION:
PREEXISTING DISORDERS OF THE FOLLOWING ORGANS (OR ORGAN SYSTEMS) MAY BE
AGGRAVATED BY EXPOSURE TO THIS MATERIAL:
SKIN, LUNG (FOR EXAMPLE, ASTHMA-LIKE CONDITIONS)
SYMPTOMS:
SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING,
SWALLOWING, AND/OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE:
STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING, DIARRHEA), IRRITATION
(NOSE, THROAT, AIRWAYS), ABDOMINAL PAIN
TARGET ORGANS: NO DATA
CARCINOGENICITY:
THIS MATERIAL IS NOT LISTED AS A CARCINOGEN BY THE INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC), THE NATIONAL TOXICOLOGY PROGRAM (NTP), OR THE
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA). USED MOTOR OIL HAS
BEEN SHOWN TO CAUSE SKIN CANCER IN LABORATORY ANIMALS CONTINUALLY EXPOSED
BY REPEATED APPLICATIONS. AVOID PROLONGED OR REPEATED SKIN CONTACT.
REPRODUCTIVE HAZARD:
THERE ARE NO DATA AVAILABLE FOR ASSESSING RISK TO THE FETUS FROM MATERNAL
EXPOSURE TO THIS MATERIAL.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. CONCENTRATION
DISTILLATES (PETROLEUM), 64742-54-7 >/=60-<70%
HYDROTREATED HEAVY PARAFFINIC
HYDROTREATED LIGHT 64742-55-8 >/=10-<15%
PARAFFINIC DISTILLATE
PETROLEUM DISTILLATE NJTS# 800986-5245P >/=10-<15%
| 4. FIRST AID MEASURES | |
EYES:
IF SYMPTOMS DEVELOP, MOVE INDIVIDUAL AWAY FROM EXPOSURE AND INTO FRESH AIR.
FLUSH EYES GENTLY WITH WATER WHILE HOLDING EYELIDS APART. IF SYMPTOMS
PERSIST OR THERE IS ANY VISUAL DIFFICULTY, SEEK MEDICAL ATTENTION.
SKIN:
REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND WATER. IF
SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. LAUNDER CLOTHING BEFORE REUSE.
INGESTION:
SEEK MEDICAL ATTENTION. IF INDIVIDUAL IS DROWSY OR UNCONSCIOUS, DO NOT GIVE
ANYTHING BY MOUTH; PLACE INDIVIDUAL ON THE LEFT SIDE WITH THE HEAD DOWN.
CONTACT A PHYSICIAN, MEDICAL FACILITY, OR POISON CONTROL CENTER FOR ADVICE
ABOUT WHETHER TO INDUCE VOMITING. IF POSSIBLE, DO NOT LEAVE INDIVIDUAL
UNATTENDED.
INHALATION:
IF SYMPTOMS DEVELOP, MOVE INDIVIDUAL AWAY FROM EXPOSURE AND INTO FRESH AIR.
IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. IF BREATHING IS DIFFICULT,
ADMINISTER OXYGEN. KEEP PERSON WARM AND QUIET; SEEK IMMEDIATE MEDICAL
ATTENTION.
NOTES TO PHYSICIAN:
HAZARDS:
ACUTE ASPIRATION OF LARGE AMOUNTS OF OIL-LADEN MATERIAL MAY PRODUCE A
SERIOUS ASPIRATION PNEUMONIA. PATIENTS WHO ASPIRATE THESE OILS SHOULD BE
FOLLOWED FOR THE DEVELOPMENT OF LONG-TERM SEQUELAE. REPEATED ASPIRATION OF
SMALL QUANTITIES OF MINERAL OIL CAN PRODUCE CHRONIC INFLAMMATION OF THE
LUNGS (I.E. LIPOID PNEUMONIA) THAT MAY PROGRESS TO PULMONARY FIBROSIS.
SYMPTOMS ARE OFTEN SUBTLE AND RADIOLOGICAL CHANGES APPEAR WORSE THAN
CLINICAL ABNORMALITIES. OCCASIONALLY, PERSISTENT COUGH, IRRITATION OF THE
UPPER RESPIRATORY TRACT, SHORTNESS OF BREATH WITH EXERTION, FEVER, AND
BLOODY SPUTUM OCCUR. INHALATION EXPOSURE TO OIL MISTS BELOW CURRENT
WORKPLACE EXPOSURE LIMITS IS UNLIKELY TO CAUSE PULMONARY ABNORMALITIES.
TREATMENT: NO INFORMATION AVAILABLE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY, DRY POWDER, FOAM, CARBON DIOXIDE (CO2)
HAZARDOUS COMBUSTION PRODUCTS:
MAY FORM:
CARBON DIOXIDE AND CARBON MONOXIDE, OXIDES OF SULFUR, NITROGEN AND
PHOSPHORUS, HYDROCARBONS
PRECAUTIONS FOR FIRE-FIGHTING:
NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE
PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. WEAR FULL FIREFIGHTING
TURN-OUT GEAR (FULL BUNKER GEAR), AND RESPIRATORY PROTECTION (SCBA). DO NOT
DIRECT A SOLID STREAM OF WATER OR FOAM INTO HOT, BURNING POOLS OF LIQUID
SINCE THIS MAY CAUSE FROTHING AND INCREASE FIRE INTENSITY. FROTHING CAN BE
VIOLENT AND POSSIBLY ENDANGER ANY FIREFIGHTER STANDING TOO CLOSE TO THE
BURNING LIQUID.
FLAMMABILITY CLASS FOR FLAMMABLE LIQUIDS: COMBUSTIBLE LIQUID CLASS IIIB
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
FOR PERSONAL PROTECTION SEE SECTION 8. SPILLS OF THIS MATERIAL ARE VERY
SLIPPERY.
ENVIRONMENTAL PRECAUTIONS:
PREVENT RUN-OFF TO SEWERS, STREAMS OR OTHER BODIES OF WATER. IF RUN-OFF
OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS OCCURRED.
METHODS FOR CLEANING UP:
PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF
SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF
SPILL TO PREVENT SPREADING, PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID
MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT, OR OTHER ABSORBENT
MATERIAL AND SHOVELED INTO CONTAINERS.
OTHER INFORMATION:
NOTIFY THE PROPER AUTHORITIES AS REQUIRED THAT A SPILL HAS OCCURRED.
COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED
CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL
HAZARD PRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED.
STORAGE: NO DATA
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8:
ACGIH:
TIME WEIGHTED AVERAGE: 5 MG/M3 MIST.
ACGIH:
SHORT TERM EXPOSURE LIMIT: 10 MG/M3 MIST.
ACGIH NIC:
TIME WEIGHTED AVERAGE: 0.2 MG/M3 INHALABLE FRACTION.
DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0:
OSHA Z1:
PERMISSIBLE EXPOSURE LIMIT: 500 PPM
OSHA Z1:
PERMISSIBLE EXPOSURE LIMIT: 2,000 MG/M3
OSHA Z1A:
TIME WEIGHTED AVERAGE: 400 PPM
OSHA Z1A:
TIME WEIGHTED AVERAGE: 1,600 MG/M3
US CA OEL:
TIME WEIGHTED AVERAGE (TWA): 400 PPM
PERMISSIBLE EXPOSURE LIMIT (PEL):
US CA OEL:
TIME WEIGHTED AVERAGE (TWA): 1,600 MG/M3
PERMISSIBLE EXPOSURE LIMIT (PEL):
ACGIH:
TIME WEIGHTED AVERAGE: 5 MG/M3 MIST.
ACGIH:
SHORT TERM EXPOSURE LIMIT: 10 MG/M3 MIST.
ACGIH NIC:
TIME WEIGHTED AVERAGE: 0.2 MG/M3 INHALABLE FRACTION.
GENERAL ADVICE:
THESE RECOMMENDATIONS PROVIDE GENERAL GUIDANCE FOR HANDLING THIS PRODUCT.
PERSONAL PROTECTIVE EQUIPMENT SHOULD BE SELECTED FOR INDIVIDUAL
APPLICATIONS AND SHOULD CONSIDER FACTORS WHICH AFFECT EXPOSURE POTENTIAL,
SUCH AS HANDLING PRACTICES, CHEMICAL CONCENTRATIONS AND VENTILATION. IT IS
ULTIMATELY THE RESPONSIBILITY OF THE EMPLOYER TO FOLLOW REGULATORY
GUIDELINES ESTABLISHED BY LOCAL AUTHORITIES.
EXPOSURE CONTROLS:
GENERAL ROOM VENTILATION SHOULD BE ADEQUATE FOR NORMAL CONDITIONS OF USE.
HOWEVER, IF UNUSUAL OPERATING CONDITIONS EXIST, PROVIDE SUFFICIENT
MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE
BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW LEVELS THAT CAUSE KNOWN,
SUSPECTED OR APPARENT ADVERSE EFFECTS.
EYE PROTECTION:
NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. WEAR SPLASH-PROOF SAFETY
GOGGLES IF MATERIAL COULD BE MISTED OR SPLASHED INTO EYES.
SKIN AND BODY PROTECTION:
WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER).
WEAR NORMAL WORK CLOTHING INCLUDING LONG PANTS, LONG-SLEEVED SHIRTS AND
FOOT COVERING TO PREVENT DIRECT CONTACT OF THE PRODUCT WITH THE SKIN.
LAUNDER CLOTHING BEFORE REUSE. IF SKIN IRRITATION DEVELOPS, CONTACT YOUR
FACILITY HEALTH AND SAFETY PROFESSIONAL OR YOUR LOCAL SAFETY EQUIPMENT
SUPPLIER TO DETERMINE THE PROPER PERSONAL PROTECTIVE EQUIPMENT FOR YOUR
USE.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION IS NOT REQUIRED UNDER NORMAL CONDITIONS OF USE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
FORM: NO DATA
COLOR: AMBER
ODOR: NO DATA
BOILING POINT/BOILING RANGE: 575.00 DEG. F / 575 DEG. F @ 760.00 MMHg
pH: NO DATA
FLASH POINT (>)430.00 DEG. F / 221.11 DEG. C
EVAPORATION RATE: NO DATA
EXPLOSION LIMITS: NO DATA
VAPOR PRESSURE: NO DATA
VAPOR DENSITY: (<)1 (AIR=1)
DENSITY:
0.8890 G/CM3 @ 60.01 DEG. F / 15.56 DEG. C
7.39 LB/GAL 7.39 LB/GAL @ 60.00 DEG. F / 15.56 DEG. C 60.1 DEG. F /
15.6 DEG. C
SOLUBILITY: NO DATA
PARTITION COEFFICIENT n-OCTANOL/WATER: NO DATA
AUTOIGNITION TEMPERATURE: NO DATA
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID:
AVOID CONTACT WITH: EXCESSIVE HEAT
INCOMPATIBLE PRODUCTS:
AVOID CONTACT WITH: STRONG OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY FORM:
CARBON DIOXIDE AND CARBON MONOXIDE, OXIDES OF SULFUR, NITROGEN AND
PHOSPHORUS, HYDROCARBONS
HAZARDOUS REACTIONS: NO DATA
THERMAL DECOMPOSITION: NO DATA
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE ORAL TOXICITY:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
LD50 RAT: >15 G/KG
PETROLEUM DISTILLATE:
LD50 RAT: >5,000 MG/KG
ACUTE INHALATION TOXICITY:
ACUTE DERMAL TOXICITY:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
LD50 RABBIT: >5 G/KG
PETROLEUM DISTILLATE:
LD50 RABBIT: >5,000 MG/KG
| 12. ECOLOGICAL INFORMATION | |
AQUATIC TOXICITY:
ACUTE AND PROLONGED TOXICITY TO FISH: NO DATA
ACUTE TOXICITY TO AQUATIC INVERTEBRATES: NO DATA
ENVIRONMENTAL FATE AND PATHWAYS: NO DATA
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHODS:
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS. FOR ASSISTANCE WITH YOUR WASTE MANAGEMENT NEEDS - INCLUDING
DISPOSAL, RECYCLING AND WASTE STREAM REDUCTION, CONTACT ASHLAND
DISTRIBUTION'S ENVIRONMENTAL SERVICES GROUP AT 800-637-7922.
| 14. TRANSPORT INFORMATION | |
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT PACKAGE
SIZE, QUANTITY, END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED.
CONSULT SHIPPING DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE
SHIPMENT.
| 15. REGULATORY INFORMATION | |
CALIFORNIA PROP. 65:
PROPOSITION 65 WARNINGS ARE NOT REQUIRED FOR THIS PRODUCT BASED ON THE
RESULTS OF A RISK ASSESSMENT.
SARA HAZARD CLASSIFICATION: ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD:
SARA 313 COMPONENT(S):
HMIS NFPA
HEALTH 1 1
FLAMMABILITY 1 1
REACTIVITY 0 0
OTHER
| 16. OTHER INFORMATION | |
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE
ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS MSDS HAS BEEN
PREPARED BY ASHLAND'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT
(1-800-325-3751).